Use Your Aperol To Upgrade This Classic Cocktail When Spritz Season Is Over - Tasting Table
Briefly

"Since Aperol has a natural orange flavor note, I believe it can make a great cointreau substitute in margaritas. It will also add a slight bitter component to the margarita."
"You can add Aperol to pretty much any margarita recipe, and it won't take much of the apéritif to enhance the flavor. Just one ounce should do the trick."
Read at Tasting Table
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