The main difference between the two is the intended usage of the software. Citrix XenServer targets personal users & small to medium-sized businesses, while VMware vSphere ESXi is for small to medium-sized businesses only, not personal use.
Both run Bare Metal hypervisors & support x86 and x64 architecture, with VMware supporting full virtualization. Citrix supports more storage options like FCoE, SSD, USB, SATA, SAS, NFS, iSCSI, while VMware supports FCoE and SSD but not USB, SATA, SAS, NFS, iSCSI.
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