The first Clásico of the season between Real Madrid and Barcelona is set for October 26, where Madrid's star Kylian Mbappé will make his debut.
Barcelona, under new head coach Hansi Flick, has made a perfect start to the season, winning all six fixtures, while Madrid is four points behind.
The scheduling means Barcelona will have one fewer rest day than Madrid due to their Champions League match against Bayern Munich on October 23.
Last season, Madrid completed a double over Barcelona, with both league games decided by Jude Bellingham winners in stoppage time.
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